دانلود مقاله ISI انگلیسی شماره 157830
عنوان انگلیسی
Ultrathin α-MnO2 Nanosheets Wrapped on Acanthosphere-like Microspheres with Highly Reversible Performance for Energy Storage
کد مقاله سال انتشار تعداد صفحات مقاله انگلیسی ترجمه فارسی
157830 2017 32 صفحه PDF سفارش دهید
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منبع

Publisher : Elsevier - Science Direct (الزویر - ساینس دایرکت)

Journal : Electrochimica Acta, Volume 247, 1 September 2017, Pages 745-753

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چکیده انگلیسی

Architecturally assembling primary building blocks into the expected geometric heterostructure is a tremendous challenge due to the interfaces dislocation and stretch resulting from the lattice-mismatch between heterogeneous building blocks. Although different dimensional nanomaterials have been synthesized, the branched acanthosphere-like hierarchical architecture is needed to be developed and the growth mechanism should be investigated. Here we design and fabricate an acanthosphere-like NiCo2O4@α-MnO2 heterostructures architecture by an “in situ growth” technique of two-steps hydrothermal method. The as-prepared acanthosphere-like NiCo2O4@α-MnO2 microspheres (denoted as AM-NCM) have a diameter of 5 ∼ 7 um with a highly open and interstitial three dimensional (3D) architecture formed by α-MnO2 ultrathin nanosheets leading to faster ion diffusion and improved charge transfer kinetics. Therefore, the hybrid electrodes exhibits exceptional specific capacitances of 695 F g−1 (2.17 F cm−2) at the current densities of 3.2 A g−1 (10 mA cm−2) and good cycling electrochemical stability with only 2.4% capacitance loss after 1000 cycles and still maintains 92% of its initial value after 6000 cycles. The outstanding performance of the branched AM-NCM reveals its potential to be a promising material for energy storage, and also inspires continued research on the formation of branched hierarchical architecture as energy storage materials.

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