دانلود مقاله ISI انگلیسی شماره 54191
ترجمه فارسی عنوان مقاله

بررسی کاهش رتبه نوری در سلول های خورشیدی پلیمری مخلوط با مشتقات مختلف فولرن

عنوان انگلیسی
Investigation of photodegradation in polymer solar cells blended with different fullerenes derivatives
کد مقاله سال انتشار تعداد صفحات مقاله انگلیسی
54191 2014 9 صفحه PDF
منبع

Publisher : Elsevier - Science Direct (الزویر - ساینس دایرکت)

Journal : Solar Energy Materials and Solar Cells, Volume 123, April 2014, Pages 150–158

ترجمه کلمات کلیدی
میل الکترون فولرین؛ اتصال نامتجانس فله ای فولرین
کلمات کلیدی انگلیسی
P3HT:fullerene bulk heterojunction; Fullerene electron affinity; ICBA; PCBM; Photodegradation; FTIR
پیش نمایش مقاله
پیش نمایش مقاله  بررسی کاهش رتبه نوری در سلول های خورشیدی پلیمری مخلوط با مشتقات مختلف فولرن

چکیده انگلیسی

To fabricate long lifetime polymer solar cells, understanding the fundamental aspects controlling the performances, stability and degradation of the devices is essential. In this study, we compare the chemical and electrical degradation behaviors of polymer solar cells based on active layers of semi-crystalline p-type polymer poly(3hexylthiophene) (P3HT) and different fullerene derivatives as acceptors. Photodegradation study by UV–visible and Fourier transform infrared (FTIR) spectroscopy and photovoltaic performance study by current–voltage measurement were done to understand and compare air stability of P3HT blended with different fullerenes. The used acceptors are indene-C(60) bisadduct (ICBA) and phenyl-C61-butyric acid methyl ester (PCBM). The obtained results show that solar cells fabricated from PCBM as acceptor are more stable than those based on ICBA. Based on the spectroscopic and electrical measurement results, it is safe to conclude that PCBM contributes more to stability of P3HT than ICBA, and that the degradation behavior is compatible with recently proposed mechanisms. Chemical properties of ICBA such as the low electron affinity could be responsible for the relative low stability of the device.