طراحی و ساخت کامپوزیت های مبتنی بر مورفولوژی کنترل نانولوله های کربنی / پلی آمید 6 به عنوان مواد عایق الکتریکی دارای هدایت حرارتی بالا و مدول الاستیک

Electrically insulating polymer materials having high thermal conductivity and elastic modulus are in high demand for next-generation electric machines and electronic devices. Carbon nanotubes (CNTs) show extremely high thermal conductivity and elastic modulus; however, even the addition of a few CNTs to polymers leads to them losing their electrically insulating properties. Herein, morphologically controlled multiwalled CNT (MWCNT)/polyamide-6 (PA6)/poly(p-phenylene sulfide) (PPS) composites, having high thermal conductivity, electrical insulation and elastic modulus, were designed and fabricated. First, MWCNT/PA6/PPS/EGMA composites comprising a PA6 matrix and MWCNT-localized PPS domains surrounded by shell-layers formed from poly(ethylene-co-glycidyl methacrylate) (EGMA) were prepared. The thermal conductivity of the composites was improved without losing the volume resistivity. However, these composites showed low elastic modulus, especially at high temperature, due to MWCNT localization and the existence of EGMA. Therefore, MWCNT/PA6/PPS/(3-glycidyloxypropyl)trimethoxysilane (GOPTS) composites having a novel morphology were designed and fabricated using GOPTS as a highly reactive shell-forming agent. In this composite, the MWCNT ends were capped with nano-sized PPS domains (MWCNT-PPS nanodomain-linked structure) to prevent electrically conductive paths forming, and MWCNT-PPS nanodomain-linked structures were uniformly dispersed in the PA6 matrix, leading to much enhanced elastic modulus and heat resistance in addition to improved thermal conductivity and electrically insulating properties. These composites containing CNT-nanodomain-linked structures are promising as electrically insulating materials for various applications including high-performance electric machines and electronic devices.